Halogen Bonding beyond Crystals in Materials Science
نویسندگان
چکیده
منابع مشابه
Fluorinated liquid crystals formed by halogen bonding.
New, halogen-bonded fluorinated mesogens are reported; the expected microphase separation associated with perfluoroalkyl chains is surprisingly absent in the mesophase.
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The structural features of a molecule are determined by the covalent bonds within the molecule. Modification of the structure requires the breaking and creation of covalent bonds. Similarly, the intrinsic reactivity of a molecule arises from the covalently bonded functional groups and active sites on a molecule. Again, changing the properties requires modifications of the covalent bonds. Even i...
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The design and synthesis of mechanically responsive materials is interesting because they are potential candidates to convert thermal energy into mechanical work. Reported in this paper are thermosalient effects in a series of halogen derivatives of salinazids. The chloro derivative, with higher electronegativity and a weaker inter-halogen bond strength (Cl⋯Cl) exhibits an excellent thermal res...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry B
سال: 2019
ISSN: 1520-6106,1520-5207
DOI: 10.1021/acs.jpcb.9b07035